17-18 November 2023
Taras Shevchenko National University of Kyiv and Shizuoka University
Europe/Kiev timezone

Raman spectroscopy study on Cu2ZnSnS4-based nanocrystals and nanocomposites

17 Nov 2023, 14:15
15m
248 (Taras Shevchenko National University of Kyiv and Shizuoka University)

248

Taras Shevchenko National University of Kyiv and Shizuoka University

4 Akademika Hlushkova Avenue, Kyiv, 03680

Speaker

Anatolii Karnaukhov (V.Ye. Lashkaryov Institute of Semiconductor Physics of the NASU)

Description

The quaternary semiconductor Cu2ZnSnS4 (CZTS) and related compounds is a promising material for photovoltaic applications, thermoelectric and other applications related with alternative energy conversion and storage [1]. Significant research efforts have been made to obtain CZTS with superior structural quality, as well as the development of more efficient characterisation techniques for the detection of structural imperfections and impurity phases [2].
Here, we investigate the CZTS nanocrystals (NCs) obtained by a low-temperature "green" aqueous colloidal synthesis in the form of liquid "inks". Because most device applications require thin films with well defined parameters, we investigated CZTS NC films formed by drop-casting, spin- and spray-coating, with subsequent thermal or photonic annealing as simple, fast, and scalable fabrication methods. We demonstrate the possibilities of structural characterisation of such NCs, their heterostructures and NC/polymer composites by Raman spectroscopy. [2,3]

Topics Session A. Physics of condensed matter and spectroscopy

Primary authors

Anatolii Karnaukhov (V.Ye. Lashkaryov Institute of Semiconductor Physics of the NASU) Mykhailo Valakh (V. Lashkaryov Institute of Semiconductors Physics, National Academy of Sciences of Ukraine, Kyiv, Ukraine. ) Nazar Mazur Oleksandr Selyshchev (Semiconductor Physics, Chemnitz University of Technology, 09107 Chemnitz, Germany.) Olga Kapush (Department of Optics and Spectroscopy, V. Lashkaryov Institute of Semiconductors Physics, National Academy of Sciences of Ukraine, Kyiv, Ukraine. ) Volodymyr Dzhagan (V. Lashkaryov Institute of Semiconductors Physics, National Academy of Sciences of Ukraine, 03038 Kyiv, Ukraine) Volodymyr Yukhymchuk Yevhenii Havryliuk (Dr.)

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