25-26 September 2020
Taras Shevchenko National University of Kyiv
Europe/Kiev timezone

Features of adsorption, mechanical properties of nano composites of multiwalled carbon nanotubes and polyethylene, polyvinyl chloride, porous polystyrene

26 Sep 2020, 15:42
4m
Online (Taras Shevchenko National University of Kyiv)

Online

Taras Shevchenko National University of Kyiv

64/13, Volodymyrska Street, City of Kyiv, Ukraine, 01601

Speaker

Mychaylo BEZZUBCEV (Taras Shevchenko National University of Kyiv)

Description

The concentration dependence of the elastic module E(C) in polyvinyl chloride (C2H3Cl)n + multiwalled carbon nanotubes (MWCNT) can be described by a percolation model with the extremely low percolation “threshold” in the range 0.02 ÷ 0.1%.
The Poisson coefficient μ is equal to ratio of relative transversal compression ε┴ to relative longitudinal lengthening ε║ and equal [1]:
μ = ε┴/ε║ = 1/2[1 + 1/1-(V║/V┴)2], (1)
Debye temperature θD was determined after the formula [1]:
θD = h/kB(9NAρ/4πA)1/3 . (1/V║3 + 2/V┴3)1/3, (2)
where kB - Bol'cman constant, h - Plank constant, NA - Avogadro number, A - middle gram-molecular mass, ρ - density, V║ - longitudinal ultrasonic (US) velocity, V┴ - transversal US velocity.
The account of dispersion of elastic mechanical vibrations energy of SiO2+Si plate on the structure defects results in expression for frequency of free vibrations of disk [1]:
ω = [(Dβ2/ρhR4 - 2π2(Q-1/T)2]1/2, (3)
where cylindrical inflexibility of plate D = Eh3/12(1 - μ)2 determined through the elastic module
E = 12ρω2R4(1 - μ)2/β2h2, (4)
plate thickness h and Poisson coefficient μ, β – is a dimensionless coefficient the value of which depends on the number of key circumferences, ρ – the specific density of plate, R - the disk radius, Q-1 – internal friction (IF), T – the disk vibrations period.
REFERENCES
[1] A.P. Onanko, D.V. Charnyi, Y.A. Onanko, M.P. Kulish etc. Conference Proceedings of 18 Geoinformatics: theoretical and applied aspects, 2019, 1-5 (2019). DOI: https://doi.org/10.3997/2214-4609.201902110.

Topics Session A. Physics of condensed matter and spectroscopy

Primary author

Mychaylo BEZZUBCEV (Taras Shevchenko National University of Kyiv)

Co-authors

Tatiana BUSKO (Taras Shevchenko National University of Kyiv) Yuriy ONANKO (Taras Shevchenko National University of Kyiv) Dmitro CHARNYI (Taras Shevchenko National University of Kyiv) Anatoliy ONANKO (Taras Shevchenko National University of Kyiv) Mykola KULISH (Taras Shevchenko National University of Kyiv) Oksana DMYTRENKO (Taras Shevchenko National University of Kyiv) Tatiana PINCHUK-RUGAL (Taras Shevchenko National University of Kyiv) Maksim ALIEKSANDROV (Taras Shevchenko National University of Kyiv) Lilia KUROCHKA (Taras Shevchenko National University of Kyiv)

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